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Skinner appears to be continuing with the five-at-the-back formation, meaning that Anouk Denton and Li Mengwen will likely occupy the wing-back positions, with Amber Tysiak and Shelina Zadorsky joining Cooke in the middle of the defence.
Oona Siren and captain Katrina Gorry continue in the heart of the midfield for the second game in succession.
In attack, the aforementioned Piubel will hope to make an impact on her first start in the WSL as part of a three-pronged attack alongside Viviane Asseyi and Riko Ueki.
Skinner has nine options to choose from on her substitutes bench, which includes youngster Soraya Walsh for the first time this season. Megan Walsh, Kirsty Smith, Marika Bergman Lundin, Dagný Brynjarsdóttir, Manuela Paví, Halle Houssein, Harries and Sáez complete the matchday squad.
Watch the match live on the WSL YouTube channel, with coverage beginning five minutes before the scheduled 3pm (BST) kick off!
West Ham United: Szemik, Tysiak, Cooke, Zadorsky, Denton, Gorry ©, Siren, Mengwen, Piubel, Ueki, Asseyi
Subs: M.Walsh (GK), Smith, Bergman Lundin, Brynjarsdóttir, Paví, Harries, Sáez, Houssein, S.Walsh
Arsenal: van Domselaar, Fox, Codina, Catley, Mariona, Little ©, McCabe, Maanum, Walti, Foord, Russo
Subs: Zinsberger (GK), Williamson, Reid, Cooney-Cross, Kuhl, Mead, Kafaji, Hurtig, Blackstenius
Referee: Tom Parsons